The temperature of flame varies depending on the substance being combusted and the extent to which the fuel and oxidizer have been pre-mixed. One of the lowest temperature of flame is the "safety flame" of a Bunsen burner, to demonstrate it is on — about 300 °C (572 °F), while the hottest is carbon subnitride burning in pure oxygen, with a temperature of 4987 °C (9008 °F), almost as hot as the surface of the Sun. The nuclear "flame" that heats the Sun is not a chemical flame at all, but it does have an extremely high temperature — the temperature of flame at the Sun's core is estimated at over 13,000,000 °C.

When the fuel and oxidizer are mixed well, the temperature of flame is higher, as the reaction proceeds more quickly and generates more heat. When the fuel and oxidizer are not mixed at all prior to combustion, the reaction occurs imperfectly, generating less total heat. This is typical in the case of burning wood, where hot gases carry away unburned wood particles.

The temperature of flame of a blow torch is about 1,300 °C (2,372 °F), a candle 1,400 °C (2,552 °F), and an oxyacetylene torch at 3,000°C. The temperature of flame of burning cyanogen is second only to carbon subnitride is over 4525°C (8180°F). In cyanogen and carbon subnitride, the high temperature is derived from the large number of available carbon atoms — two in the former, four in the latter -- as these carbon atoms combine with oxygen during the process of combustion, they release excess energy in the form of heat.

The color of a flame is often related to its temperature, although the molecule being burned is relevant as well. Light resulting just from temperature is called blackbody radiation, and ranges from red at 1000 K to orange/yellow at 3000 K to white or light blue at temperatures above 5000 K.