What is Oxidation?

science engineering

A freshly-cut apple turns brown, a bicycle fender becomes rusty and a copper penny suddenly turns green. What do all of these events have in common? They are all examples of a process called oxidation.

Oxidation is the interaction between oxygen molecules and all the different substances they may contact, from metal to living tissue. Sometimes oxidation is not such a bad thing, as in the formation of super-durable anodized aluminum. Other times oxidation can be destructive, such as the rusting of an automobile or the spoiling of fresh fruit.

We often used the words 'oxidation' and 'rust' interchangeably, but not all materials which interact with oxygen molecules actually disintegrate into rust. In the case of iron, the oxygen creates a slow burning process, which results in the brittle brown substance we call rust. When oxidation occurs in copper, on the other hand, the result is a greenish coating called copper oxide. The metal itself is not weakened by oxidation, but the surface develops a patina after years of exposure to air and water.

The process of oxidation depends on the amount of oxygen present in the air and the nature of the material it touches. True oxidation happens on a molecular level -- we only see the large-scale effects as the oxygen causes free radicals on the surface to break away. In the case of fresh fruit, the skin usually provides a barrier against oxidation. This is why most fruits and vegetables arrive in good condition at the grocery store. Once the skin has been broken, however, the individual cells come in direct contact with air and the oxygen molecules start burning them. The result is a form of rust we see as brownish spots or blemishes.

Oxidation can also be a problem for car owners, since the outermost layers of paint are constantly exposed to air and water. If the car's outer finish is not protected by a wax coating or polyurethane, the oxygen molecules in the air will eventually start interacting with the paint. As the oxygen burns up the free radicals contained in the paint, the finish becomes duller and duller. Restoration efforts may include removing several layers of affected paint and reapplying a new layer of protectant. This is why professional car detailers recommend at least one layer of wax or other protectant be used every time the car is washed.

The secret of preventing oxidation is to provide a layer of protection between the exposed material and the air. This could mean a wax or polyurethane coating on a car, a layer of paint on metal objects or a quick spray of an anti-oxidant, like lemon juice, on exposed fruit. Destructive oxidation cannot occur if the oxygen cannot penetrate a surface to reach the free radicals it craves.

This is why 'stainless steel' doesn't rust and ordinary steel does. The stainless steel has a thin coating of another metal which does not contain free radicals. Regular steel may be painted for protection against oxidation, but oxygen can still exploit any opening, no matter how small. This is why you may find a painted metal bicycle still damaged by rust.

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New: Discuss this Article

Posted by: anon414
Does oxidizing have anything to do with bacteria? I have an experiment and the question is "Does vitamin C prevent fresh food from rotting (oxidizing)? My teacher said the topic was bacteria.
Posted by: Este
if you have an emulsion, and with the effect of time or temperature, it becomes thin and watery, what is the scientific term for this occurrence? It's not oxidation is it?
Posted by: Este
If a skin care product becomes rancid, is this considered oxidation?
Posted by: juliette
is copper sulfate and copper oxide the same thing?

Posted by: anon2851
Ummm... Metals don't contain free radicals. Free radicals are involved in some oxidation processes, but the main reason some metals oxidize in air and others don't is that for many metals, once they are coated with oxide, they do not oxidize further. The reason stainless steel does not rust is that it is mixed with nickel and chromium, and these form a layer of oxide that prevents the bulk from oxidizing. Something similar occurs with aluminum; aluminum becomes coated with aluminum oxide, which under ordinary conditions prevents the metal from oxidizing further. However, if aluminum is powder and mixed with a powdered oxidizer, it can burn quite rapidly; in fact this is used as a "flash powder" for fireworks.
Posted by: tu2dogs
what about protection against the oxidation rxn between free O2 and steel by utilizing a cathodic protection mechanism such that a constant supply of electrons is emitted from the surface requiring protection. In the case of the classic experiment wherein steel wool is partly immersed in water, could not one test this hypotheses by passing a low level charge through the steel wool?
Posted by: anon4060
I'm doing this science experiment about whether oxidation occurs in apples in different levels of ph water. do you think that ph levels will have an effect?

Posted by: anon4210
Why must oxidation be accompanied by a reduction?
Posted by: anon4267
Is there a difference between oxidation and oxidization?
Posted by: anon4350
I was wondering if oxidation would have any effect on the pH.
Posted by: anon4516
What about oxidation in the body? Do antioxidants help prevent that process?
Posted by: airin
Hello, I was very happy to find this article online because I'm doing my science fair project on which type of antioxidants best prevents oxidation in an apple. So I'm trying to read up the most I can on the process of oxidation. Can someone tell me a little bit more about the chemical reactions between the substance in the apple and the oxygen - which creates oxidation? Any other information would be extremely helpful as well. Thank you!
Posted by: anon4842
I was glad to find this article although there are some errors it will do just fine for my science fair project and report. Any comments on oxidation being used in invisible ink?
Posted by: anon4966
Hello, I was very happy to find this article online because I'm doing my science fair project on which type of antioxidants best prevents oxidation in an apple. So I'm trying to read up the most I can on the process of oxidation. Can someone tell me a little bit more about the chemical reactions between the substance in the apple and the oxygen - which creates oxidation? Any other information would be extremely helpful as well. Thank you!
Posted by: anon5071
I am trying to do my homework and my teacher said that I have to find some everyday examples of oxidation. Can you please give me some pointers? I'm stuck:(
Posted by: anon5611
I'm doing a science project on antioxidants, and I need to find out how exactly antioxidants prevent oxidation.

Posted by: anon5627
Hi, I'm doing this project, and I have to say it is really fun to see object oxidate. Thanks for helping me.
Posted by: anon5675
hi! I'm doing a science fair experiment on oxidation on pennies. i was wondering does oxidation happen over time or does there have to be a chemical laid on top to make oxidation happen? thanks!
Posted by: anon5929
hi!! i'm doing a science project on oxidation i need help on how oxidation affects apples and how they rot. i need help please reply ty!!!
Posted by: anon7202
I have to get this thing about oxidization and why things don't oxidize with vit. C and something like elplyhms or whatever. Soo... any pointers?
Posted by: sciencechic1
please mail me with tips and everything for my science fair project. i need help on the things that vitamin C does to fruits and vegetables and oxidation!!!!
Posted by: anon8413
"Posted by: juliette

is copper sulfate and copper oxide the same thing?"

No, Copper Sulphate is when copper, or something containing Copper, reacts with Sulphur or something with Sulphur in it. It contains S (sulphur) and Cu (copper) molecules.

Copper oxide is formed when Copper, or something containing Copper, reacts with Oxygen or something with Oxygen in it. It contains O (oxygen) and Cu (copper) molecules.

Posted by: anon9504
How is oxidation something you need to determine iodide content in salt?

How is it involved?

Posted by: garec111
I am doing my science fair project on oxidation.

Could you tell me some things that are affected

by oxidation? Thanks!

Posted by: anon10820
in some process oxidation is required and which is very necessary ? ozone is an oxidizing agent and it is very powerful ? could you explain me why oxidation is required ?
Posted by: elijah
The above article is good. It would be better if a few redox reactions were explained in terms of oxidation number method. How about galvanic cells?
Posted by: anon11629
what do you call the loss of oxygen in a reaction? oxidation or reduction? can someone please explain the difference between the two.
Posted by: jamezter
So the more oxygen the more oxidation occurs? or the more water there is the more oxidation occurs? Let's say the water is actually RO water. Will there be any oxidation?
Posted by: anon11965
Say an apple is in a closed environment and uses up all the oxygen in oxidation, what happens to the apple after that?
Posted by: anon12326
why do humans take antioxidants?

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