What Is Hard Anodizing?

manufacturing industry

Because of its lighter weight and non-conductivity, anodized aluminum has become a popular alternative to steel in manufacturing circles. But many applications call for a process called anodizing to give aluminum a stronger surface. Essentially, anodizing involves immersing aluminum in a bath of sulfuric acid, called an electrolyte, and running a low-voltage electric current through the acid solution. The result of normal anodizing is a thin coating of aluminum oxide (rust) on the surface of the original aluminum sheet. If the acid solution is cooled to the freezing point of water and the amount of electric current increased substantially, however, the process is called hard anodizing.

Hard anodizing is more commonly found in industrial or commercial applications than in consumer products. Some aluminum cookware may be processed through hard anodizing, but regular anodizing generally produces the durable non-stick coating preferred by consumers. Hard anodizing produces a much thicker coating of aluminum oxide, penetrating holes and fissures in the surface to create a more uniform appearance than regular anodized aluminum. Aluminum sheets processed by hard anodizing may have a dark brown or black surface, but other colors can be created.

The benefits of hard anodizing aluminum instead of using stainless steel are lower overall cost and weight. Machining hard anodized aluminum is easier than penetrating a similar block of stainless steel. Hard anodizing also yields a product resistant to harsh weather, salt sprays and abrasive machining processes. Aluminum processed by hard anodizing can be only a few points away from the hardness of diamonds.

The automobile industry and the commercial cookware industry have both been long-time proponents of hard anodizing. Nonstick coatings such as Teflon® must have a reliable method for application which can create a strong adhesive bond. Hard anodizing can incorporate Teflon® or other substances during the electrolytic process. Some automotive parts also benefit from the hard anodizing process, since the finished product can withstand heat and is non-conductive. The medical field has also benefited from hard anodizing technology. The aluminum used in prosthetic joints is hard anodized for additional strength and resistance to the corrosive quality of blood.

Hard anodizing shares many characteristics with sulfuric anodizing, but the two processes have clearly different results. Hard anodizing creates a much thicker aluminum oxide surface with a stronger bond to the original aluminum layer. When shopping for new aluminum cookware, it may pay to look for the descriptions 'anodized aluminum' or 'hard anodized.' The cookware marked 'hard anodized' may prove to be more durable, though possibly a little more expensive.

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10
Is cooking in teflon, aluminum or hard anodized utensils harmful for the health? if yes what health risks do they pose? Which of these is best suited for cooking?
- anon44591
9
"Rust" is the name given to oxides of iron - aluminium oxide is not, therefore, rust.
- anon44148
8
Aluminium causes no health risks. it is associated to Alzheimer's but there is no firm evidence. its a myth, kind of like the 'blue blood' myth years ago - using stainless steel utensils in a s/s pan caused blue blood which killed the royals, but im pretty sure this came out when nylon utensils were new. anyway an antacid tablet has more aluminium in it then you will get from cooking in an aluminium pan for the rest of your life.
- anon35685
7
I'm still confused! I sell cookware at a large Macys store for a living I have a lot of people coming in - or brides that want it short simple -- kindergarten language - what is hard anodized - what product is best - will non stick hurt me -- what stainless cookware (besides All Clad) is best - what is crap! We sell Emeril, Cuisinart, Analon, All Clad, and certain Macys brands
- tlbruch
6
Here I am living in a residential area next to a small business that uses hard anodizing in a garage that no longer functions as a garage, but is loaded with high-tech equipment for the business. Aluminum is provided with coatings in this business. Sometimes I can smell odors that seem to indicate unhealthy air pollution. The owners are not covert about this business, and in fact have a splashy web site. Is there any reason to think that this well-constructed garage might be putting stuff out into the air that could be harmful to me next door?
- ylletroja
5
My grandmother told me not to buy aluminum pans, because are bad for your health? Is she correct? She told me that the aluminum is not safe, that either nonstick or stainless steel is better.

I know a lot of time ago the aluminum was prohibited because it can cause cancer??? Can you answer this question?

Thank you!

- anon5758
4
Alternate processes exist for ferrous metals such as nitriding or carbon-nitriding. This results in an extremely hard case. Also, anodizing is not necessarily "aluminum-based". Other materials can be successfully anodized such as tungsten, magnesium and molybdenum. Depends on the stability of the oxide the material forms.
- anon5549
3
To Respond to myquest: no, the anodization of Aluminum is a byproduct of the unique way that Aluminum oxidizes. Al2O3, the product of Aluminum oxidation, is hard compared to Al by itself. It forms as soon as raw Al hits the atmosphere and prevents further oxidation of the Al. Anodization further pushes and forces this process to create a thicker oxidation layer. Hope that helps.
- anon2216
2
I know anodising is an aluminum based process but does an equivalent exist for other conductive materials like ductile iron?
- myquest

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Written by Michael Pollick
Last Modified: 09 September 2009

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