I get brain freeze, but I also sometimes get a throbbing ache in my temple. It's kind of weird. I'll eat or drink something cold, and then my temples will start throbbing. I'm sure it's a form of brain freeze, but it tends to last longer.
Actual brain freeze seems to hurt right behind my eyes and across the bridge of my nose. It's a sharp pain and really doesn't last that long. When my temples throb, sometimes it's for as long as five minutes or so, whereas brain freeze lasts a minute or less. I'm not crazy about getting either kind of pain.